Applications of Boron and Its Compounds in High-Performance Composite Materials
Chapter from the book:
Fedai,
Y.
(ed.)
2025.
Innovative Approaches and Next-Generation Engineering Studies in Mechanical Engineering.
Synopsis
This study reviews the strategic and technological applications of boron and its high-performance compounds boron carbide (B4C), boron nitride (BN), and metal borides (TiB2, ZrB2) in composite materials. Boron is a strategic mineral with rich reserves, particularly in Turkey, which holds a near-monopoly position. Boron compounds are among the hardest materials after diamond, significantly enhancing the mechanical, tribological, and thermal properties of composites.
The studies demonstrate that B4C reinforcement substantially increases the hardness of aluminium (Al) matrix composites and provides full protection against Level 4 threats in ballistic armor applications. BN nanotubes and nanosheets exhibit tremendous potential for orthopedic implants, increasing fracture toughness by 86% and hardness by 129% in hydroxyapatite (HA) matrix bio-composites. Common low wettability issues in metal matrix composites (Al/ B4C) are overcome through surface modification techniques like nickel (Ni) coating, thereby strengthening the matrix-reinforcement interface bond. Furthermore, the high neutron absorption capacity of TiB2 and B4C makes them critical for nuclear reactor control rods, while hBN-based coatings significantly improve wear and corrosion resistance. Consequently, boron and its products play a pivotal role in developing next-generation, high-performance materials for industries such as aerospace, defence, and biomedical engineering.
